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CHEMISTRY OF CARBON USING CHIME SOFTWARE
 

This page uses the Chime Plug-in . If you do not have Chime the following page is now available using jmol at:

http://www.edinformatics.com/interactive_molecules/carbon_jmol.htm

 

 

The follow page requires the molecular modeling plug-in Chime which allows you to view molecules in 3-D. The molecules can be rotated, zoomed-in/out and viewed as either wireframe, sticks, ball and stick or space-filled models. If you need the plug-in, it's free from MDL Information Systems.

Carbon is found in many different compounds. It is in the food you eat, the clothes you wear, the cosmetics you use and the gasoline that fuels your car. In addition, carbon is a very special element because it plays a dominant role in the chemistry of life. The element carbon has four electrons in its valence shell (outer shell). Since this energy shell can hold eight electrons, each carbon atom can share electrons with up to four different atoms. Carbon can combine with other elements as well as with itself. This allows carbon to form many different compounds of varying size and shape.

Carbon alone forms the familiar substances graphite and diamond. Both are made only of carbon atoms. Graphite is very soft and slippery. Diamond is the hardest substance known to man. If both are made only of carbon what gives them different properties? The answer lies in the way the carbon atoms form bonds with each other.

Graphite

Notice that graphite is layered.

There are strong covalent bonds between carbon atoms in each layer. But, only weak forces exist between layers. This allows layers of carbon to slide over each other in graphite.

On the other hand, in diamond each carbon atom is the same distance to each of its neighboring carbon atoms. In this rigid network atoms cannot move. This explains why diamonds are so hard and have such a high melting point.

Diamond

Notice the strong bonding network in diamond

The 3-D coordinates for graphite and diamond are available in the MathMol Molecular Modeling Database. We urge you to download these structures to your home computer and use one of the suggested 3-D Molecular Modeling Software Packages.

The Molecule of the Month Page has recently included information on diamond located here


A third class of carbon compounds has recently been discovered. They are called fullerenes. The chime model shown below is one form composed of 60 carbons. Notice the geometric patterns of pentagons and hexagons that form the familiar icosohedron.

Fullerene

Notice the geometric patterns of pentagons and hexagons that form the familiar icosohedron.


Compounds made of Carbon

The simplest organic compounds contain molecules composed of carbon and hydrogen. The compound methane contains one carbon bonded to four hydrogen's. Ethane is another example of a simple hydrocarbon. Ethane contains two carbon atoms and four hydrogen atoms. In chemistry we use a molecular formula to show how many atoms of each element are present in a molecule. A molecular formula however does not show the structure of the molecule. Scientists often use structural formulas to show the number and arrangement of atoms in a compounds. Below the molecular formula for methane and ethane are shown. Above the molecular formula are their respective structural formula.

Although structural formulas can be very helpful they do not give a complete picture of a molecule. Structural formulas do not tell us anything about the distances between bonds, the angles formed by these bonds, or the size and shape of the molecule. Scientists use four different representation to show what molecules look like.

THE WIRE FRAME MODEL

This model clearly shows the type of atoms in the molecule, the distances between bonds, and angles associated with the atoms. Because the lines drawn are very thin, molecules can very easily be manipulated when viewed on a computer screen.

THE STICK MODEL

Atoms and bonds are represented as sticks.

THE BALL-AND-STICK MODEL

Atoms are represented by balls and bonds are represented as sticks.

THE SPACE FILLED MODEL

This model shows the space that the molecule will take up. Because of all the points required to draw this molecule on a computer screen you should expect these molecules to be very difficult to manipulate.
Wire frame Model
Stick Model
Ball and Stick Model
Space Filled Model

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